Asymmetric catalytic reduction of meso-imides
โ Scribed by Jahyo Kang; Jun Won Lee; Joo In Kim; Chongsuh Pyun
- Book ID
- 103409842
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 216 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Cyclic meso-imides such as the cyclic cis-3&disubstituted succinimides 1 farm an interesting and useful class of starting mater% in the field of asymmetric synthesis. A single, enantioselective transfoxmation, naw9y a reduction of one of the carbonyls, leads to a product with three contiguous stereo
Oxazaborolidine-Catalyzed Enantioselective Reduction of Cyclic meso-Imides. -It is found that several meso-imides can be reduced with high enantioselectivity by means of the oxazaborolidine shown in the scheme and subsequent ethanolysis or acetylation. By conversion to a benzenesulfonyllactam, it is