Asymmetric Catalytic Hydrogenation with an Optically Active Phosphinerhodium Complex in Homogeneous Solution

✍ Scribed by Prof. Dr. L. Horner; Dipl.-Chem. H. Siegel; Dipl.-Chem. H. Büthe

• Book ID: 101548035
• Publisher: John Wiley and Sons
• Year: 1968
• Tongue: English
• Weight: 121 KB
• Volume: 7
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.196809422

✦ Synopsis

Husemann on the occasion of her 60th birthday On thermal fission of trimethylsilyl N-(phenoxycarbonylf-N-(trimethy1silyl)amino carboxylates ( I ) 111 derived from p-, y-, or &-amino acids we obtained stable, distillable silyl p-, -p, and c-isocyanato carboxylates ( 2 ) .

(2a),n=2, b.p. 56--57"C/l torr;(Zb),n=3, b.p.41-42"C/0.1 torr; (Zr), n = 5, b.p. 80-81"C/0.6 torr.