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Asymmetric catalysis of carbonyl-ene and aldol reactions with fluoral by chiral binaphthol-derived titanium complex

โœ Scribed by Koichi Mikami; Tomoko Yajima; Tsuyoshi Takasaki; Satoru Matsukawa; Masahiro Terada; Tadafumi Uchimaru; Masamichi Maruta

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
876 KB
Volume
52
Category
Article
ISSN
0040-4020

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Diastereoselective and enantioselective
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Diastereo-and enantioselective carbonyl-ene reaction of glyoxylate (2) with t&substituted olefins (3) catalyzed by chiral titanium complexes (la), derived from 6,6'-dibromo-<,l'-bi-2-naphthol and diisopropoxylitanium dihaliies. is found lo provide syn-diastereomers exclusively along with a hih Mel o