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Asymmetric carbon—carbon bond formation by phase-transfer catalysis; synthesis of optically active 3-substituted dihydroisocarbostyrils

✍ Scribed by Toshio Wakabayashi; Kenzo Watanabe

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 133 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85125-x

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✦ Synopsis

Recent investigations have demonstrated that phase-transfer catalysis has a considerable potential in synthetic organic chemistry. 1 The alkylation2 of Bdicarbonyl compounds and the Wittig-Homer' reaction of carbonyl compounds have led to interesting results, but no successful examples of reactions involving asymmetric carbon-carbon bond formation have been acknowledged yet. 4

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