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Asymmetric Baeyer—Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin.

✍ Scribed by Shun-Ichi Murahashi; Satoshi Ono; Yasushi Imada


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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Asymmetric transfer hydrogenation cataly
✍ Ru Jiang; Xiaoli Sun; Wei He; Hui Chen; Yongqing Kuang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 104 KB 👁 2 views

## Abstract A novel chelated ferrocene‐based planar chiral N‐heterocyclic carbene‐Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright © 2009 John Wiley & Sons, L