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Asymmetric Aza-Morita–BaylisHillman Reaction of N-Sulfonated Imines with Activated Olefins Catalyzed by Chiral Phosphine Lewis Bases Bearing Multiple Phenol Groups

✍ Scribed by Ying-Hao Liu; Lian-Hui Chen; Min Shi

Book ID
118281227
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
197 KB
Volume
348
Category
Article
ISSN
1615-4150

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Dendritic Chiral Phosphine Lewis Bases-C
Dendritic Chiral Phosphine Lewis Bases-Catalyzed Asymmetric Aza-Morita–Baylis–Hillman Reaction of N-Sulfonated Imines with Activated Olefins
✍ Ying-hao Liu; Min Shi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB 👁 2 views

## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (