Chiral pyrimidyl, quinolyl, and pyridyl alkanols act as asymmetric autocatalysts with significant amplification of enantiomeric excess (ee) in the enantioselective addition of diisopropylzinc to pyrimidine-5-, quinoline-3-, and pyridine-3-carbaldehydes, respectively. 2-Alkynyl-5-pyrimidyl alkanol wi
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Asymmetric Autocatalysis and Its Application to Chiral Discrimination
β Scribed by Kenso Soai; Itaru Sato
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 48 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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