Asymmetric Assembly of Aromatic Rings To Produce Tetra-ortho-Substituted Axially Chiral Biaryl Phosphorus Compounds

✍ Scribed by Goushi Nishida; Keiichi Noguchi; Masao Hirano; Ken Tanaka

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 137 KB
• Volume: 119
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/ange.200700064

✦ Synopsis

Scheme 1. Synthesis of tri-ortho-substituted axially chiral biaryl phosphonates through asymmetric aryl-aryl cross-coupling.

Scheme 2. Synthesis of tetra-ortho-substituted axially chiral biaryl