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Asymmetric and Doubly Asymmetric 1,3-Dipolar Cycloadditons in the Synthesis of Enantiopure Organophosphorus Compounds

โœ Scribed by Pietrusiewicz, K. Michaz; Hozody, Wieszawa; Koprowski, Marek; Cicchi, Stefano; Goti, Andrea; Brandi, Alberto

Book ID
126801809
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
173 KB
Volume
144
Category
Article
ISSN
1042-6507

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โœ Stephen Hanessian; Roberto Margarita ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 255 KB

Dianions derived from N-Cbz and N-Boc glutamic acid esters undergo highly stereoselective anti allylation reactions at C-4. The roles of protecting groups and of the electrophile were studied. Synthetic applications and potential utility in peptidomimetic design are also described.