Asymmetric Alkynyl Additions to Aldehydes Catalyzed by Tunable Oxovanadium(V) Complexes of Schiff Bases of β-Amino Alcohols.
✍ Scribed by Sheng-Hsiang Hsieh; Han-Mou Gau
- Book ID
- 101996886
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 29 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A series of β‐sulfonamide alcohol ligands were synthesized from L‐phenylalanine. Titanium complexes of these compounds were used to catalyze the asymmetric addition of phenylacetylene to a number of aldehydes. When the conditions were optimized, 20 mol % of ligand **8a** catalyzed the r
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