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Asymmetric alkylation reaction by means of a chiral phase transfer catalyst.

โœ Scribed by J-C Fiaud


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
86 KB
Volume
16
Category
Article
ISSN
0040-4039

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Chiral salen-metal complexes as novel ca
โœ Yuri N. Belokon; Michael North; Vadim S. Kublitski; Nikolai S. Ikonnikov; Pavel ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

Chiral, salen-metal complexes have been tested as catalysts for the C-alkylation of aldimine Schiff's bases of alanine esters with alkyl bromides under phase-transfer conditions (solid sodium hydroxide, toluene, ambient temperature, 1-10% of the catalyst). The best catalyst, which was derived from a