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Asymmetric Alkylation of N-Toluenesulfonylimines with Dialkylzinc Reagents Catalyzed by Copper—Chiral Amidophosphine.

✍ Scribed by Takahiro Soeta; Kazushige Nagai; Hidetaka Fujihara; Masami Kuriyama; Kiyoshi Tomioka


Publisher
John Wiley and Sons
Year
2004
Weight
178 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Asymmetric alkylation of aromatic aldehy
✍ Günther Oehme; Irina Iovel; Edmunds Lukevics 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 56 KB 👁 2 views

Novel, specially prepared, tetrahydropyranbased g-amino alcohols (S)-2-(aminomethyl)-3-hydroxy-6-ethoxy(phenoxy)-tetrahydropyrans (I) (amino = n-Bu 2 N, piperidinyl, pyrrolidinyl, azetidinyl) were tested as catalysts in the asymmetric addition of Et 2 Zn and n-Bu 2 Zn to (hetero)aromatic aldehydes.