Transposition of the dormant methyl group from C-1 in chiral oxazolidin-2-one 2 to C-7 in a six step synthetic sequence from (IR)-camphor 5 creates a novel transfigomer 4 with sufficient n-topological bias to induce excellent levels of asymmetric induction in Lewis-acid catalysed Diels-Alder reactio
โฆ LIBER โฆ
Asymmetric aldol reactions employing a camphor-derived chiral oxazinone auxiliary.
โ Scribed by Ahn, Kyo Han; Lee, Seungkyu; Lim, Ankee
- Book ID
- 115470600
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 282 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3263
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