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Asymmetric Aldol Polymerization: Synthesis of Optically Active Polymers Based on the Asymmetric Mukaiyama Aldol Reaction

✍ Scribed by Kenichi Komura; Shinichi Itsuno


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
165 KB
Volume
203
Category
Article
ISSN
1022-1352

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Catalytic, Asymmetric Vinylogous Mukaiya
✍ Claudio Curti; Beatrice Ranieri; Lucia Battistini; Gloria Rassu; Vincenzo Zambra 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB 👁 1 views

## Abstract Denmark’s chiral bisphosphoramide/silicon tetrachloride system performs as an excellent Lewis base‐Lewis acid catalyst for the vinylogous Mukaiyama aldol reaction of pyrrole‐ and furan‐based dienoxy silanes with aromatic and heteroaromatic aldehydes. This asymmetric methodology provides