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Asymmetric addition of Davies's chiral lithium amide to prochiral vinyl phosphine oxides

✍ Scribed by Björn Bartels; Concepcion Gonzalez Martín; Adam Nelson; Matthew G. Russell; Stuart Warren


Book ID
108386498
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
243 KB
Volume
39
Category
Article
ISSN
0040-4039

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Ytterbium(III) triflate-catalyzed asymme
✍ Guigen Li; Han-Xun Wei; Jason D. Hook 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 293 KB

## Ytterbium(II1) triflate has been found to catalyze anionic additions of functionalized lithium (CXcarbalkoxyvinyl)cuprates to chiral p-toluenesulfinimines (thiooxime S-oxides) in a cosolvent system (Et#-CH2C12). This new system has made it possible to utilize those p-toluenesulfinimines of low