Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions
β Scribed by Mohiti, Maziar ;Rampalakos, Constantinos ;Feeney, Kathryn ;Leonori, Daniele ;Aggarwal, Varinder K.
- Book ID
- 121253439
- Publisher
- The Royal Society of Chemistry
- Year
- 2014
- Tongue
- English
- Weight
- 890 KB
- Volume
- 5
- Category
- Article
- ISSN
- 2041-6520
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π SIMILAR VOLUMES
lminium ion 2c participates in stereoselective nucleophilic addition reactions wkh Grfgnard reagents. Analysis of the products from reaction of 5hexenylmagnesium bromide with iminium ion 2a suggests that these reactions proceed by a polar (two electron) mechanism. The utility of this chemistry is de
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InCl 3 was used as Lewis acid in the addition of silyl enolates and allyltrimethylsilane to aromatic aldimines and cyclic N-acyliminium ions derived from 5-acetoxylactams affording b-aminocarbonyl systems and allyl adducts, respectively, in reasonable to good yields. The diastereofacial selectivity