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Asymmetric Addition of Alkenylstannanes to Alkylidene Meldrum’s Acids

✍ Scribed by Mahoney, Stuart J.; Dumas, Aaron M.; Fillion, Eric

Book ID
126019049
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
247 KB
Volume
11
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Asymmetric Addition
ChemInform Abstract: Asymmetric Addition of Alkenylstannanes to Alkylidene Meldrum′s Acids.
✍ Stuart J. Mahoney; Aaron M. Dumas; Eric Fillion 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 48 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Thioalkylation of Meldrum's Acid: Protec
Thioalkylation of Meldrum's Acid: Protected alkylidene derivatives of isopropylidene malonate
✍ Martin Eberle; Richard G. Lawton 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 640 KB

On reacting Meldrum's acid with butyraldehyde in MeCN in the presence of catalytical amounts of piperidine, we obtained a 52 % yield of the dimer ii (m.p. 1 17-1 18"), probably the same compound that was believed to be the Michaeladduct iii [13]. Reduction of dimer ii with NaBH, [5c] gave the corres