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Asymmetric Activation and Deactivation of Racemic Catalysts

โœ Scribed by Koichi Mikami; Kohsuke Aikawa

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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Asymmetric Activation/Deactivation of Ra
Asymmetric Activation/Deactivation of Racemic Ru Catalysts for Highly Enantioselective Hydrogenation Irrespective of Ketonic Substrates: Molecular Design of Dimethylbinaphthylamine for Enantiomeric Catalysts Discrimination
โœ Koichi Mikami; Toshinobu Korenaga; Yukinori Yusa; Masahiro Yamanaka ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 171 KB ๐Ÿ‘ 1 views

## Abstract Asymmetric activation and deactivation of racemic catalysts are two extremes in asymmetric catalysis. In a combination of these two protocols, higher enantioselectivity can be achieved by maximizing the difference in catalytic activity between the enantiomers of racemic catalysts throug