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Asymmetric 1,4-Addition Reaction of Arylboronic Acid to Eneone Catalyzed by Palladium with Ferrocene-Based Phosphine Ligand.

✍ Scribed by Yoshinori Suzuma; Tetsuya Yamamoto; Tetsuo Ohta; Yoshihiko Ito


Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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Chiral Heterodisulfoxide Ligands in Rhod
✍ Fuzhong Han; Guihua Chen; Xiangyang Zhang; Jian Liao 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB

## Abstract A new family of benzene‐based chiral heterodisulfoxide ligands **L1**–**L5** was synthesized in a single step. These disulfoxide ligands were applied in the rhodium‐catalyzed asymmetric 1,4‐addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chrome