ASTACUS, a time focussing neutron diffractometer based on the reverse Fourier principle

Reactions of chiral molecules in the pre

Reactions of chiral molecules in the presence of a time-non-invariant enantiomorphous influence: a new kinetic principle based on the breakdown of microscopic reversibility

✍ L.D. Barron 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 702 KB

It is suggested that conventional kinetic principles do not apply to processes involving chiral molecules in the presence of a time-non-invariant enantiomorphous influence on account of the breakdown of microscopic reversibility and hence of detailed balancing. This implies different rate constants