Association of common polarographic supporting electrolytes in acetonitrile
โ Scribed by G.A. Forcier; J.W. Olver
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 574 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0013-4686
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โฆ Synopsis
Expermmtd data are reported m conformny wtth the Fuoss-Onsager theory for the ~soclatlorl of several common8" laro ammonmm tetrafluoroborate an i$ aphtc supportmg electrolytes m acetomtrrle. Tetra-ethylvalue for Ka pert orate are completely dtssocrated, yieldmg a small negatwe Sodium perchlorate (completely dtmoctated) and potassmm perchlorate (& = 12) are more extenswely dtssocrated than prevtously reported. Imphcattons of the assoctatron data for tetramethylammonium chlorrde and tetra-ethylammomum bromtde on metal-hahde eqml~brmm studres in acetomtrde are dwussed R&mm&Des dorm&es experrmentales sent p&se&es conformement a la theone de Fuoss-Onsager, propre 51 la Qssoctat:on de divers electrolytes supports polarographrques communs dans l'ac&omtrde. Le t&raSuoroborate et le perchlorate de t&ra&hylammomum sont completement drssoctes, dhotant une valeur lQ&rement negative pour KA. Le perchlorate de sodmm (compl&ement drssoctt) et le perchlorate de potassium (& = 12) sont plus dtssoct6s qu'ant6rmurement mdrque Dtscusston des rmphcattons des don&es d'assocratton propres au chlorure de t&ram&hylammomum et au bromure de tCtra&hylammomum, quant aux equrhbres m&al-halog6nure dans l'ac&omtnle Z---Man pr&entrert expertmentelle Daten zur Theorie von Fuoss-Onsager filr dte Drssoxtatron emtger, be1 der Polarographre m Acetomtril verwendeten Lertekktrolyte Tetraiithylammomum-tetrafiuoroborat turd perchlorat smd vollstilndig drssoxuert und ergeben emen klemen negattven wert fiir KA Natrmmperchlorat (volhg dtssoxiiert) und Kahumperchlorat (ZA = 12) sind st%rker dissoxuert ah frWer angegeben wurde. Man dtskuttert dte Redeutung der Assovattonsdaten ftlr Tetramethylammomumchlond und Tetra-&hylammomumbromtd betm Studmm der MetalHIalogemdX3letchge~chte m Acetomtrtl.
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An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmental