Association and Surface Properties of Poly(ethylene oxide)−Poly(styrene oxide) Diblock Copolymers in Aqueous Solution
✍ Scribed by Mai, Shaomin; Booth, Colin; Kelarakis, Antonis; Havredaki, Vasiliki; Ryan, Anthony J.
- Book ID
- 126268678
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 107 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0743-7463
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## Abstract Amphiphilic di‐ and triblock copolymers containing poly(ethylene oxide) (PEO) as the hydrophilic block and poly(perfluorohexylethyl methacrylate) (PFMA) as the hydrophobic block were synthesized by atom‐transfer radical polymerization using hydroxy‐terminated PEO as the macroinitiator.
A number of results reported on the kinetics of exchange of triblock copolymers poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide), PEO-PPO-PEO, between micelles and the intermicellar aqueous solution are reviewed and analyzed to extract the rate constants k(+) for the entry of a copoly