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Assignment of the Phosphorus, Proton and Carbon-NMR Spectra of [(Tetrahydro-2-hydroxy-5,5-dimethyl-4H-1,4,2-oxazaphosphorin-4-yl)methyl] phosphonic acid P-Oxide

โœ Scribed by Balram Dhawan; Derek Redmore; Walter A. Boyd


Book ID
112130826
Publisher
Journal of Heterocyclic Chemistry
Year
1993
Tongue
English
Weight
137 KB
Volume
30
Category
Article
ISSN
0022-152X

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## Abstract Dielsโ€“Alder cycloaddition of a mixture of 1โ€ and 2โ€methylcyclopentadienes (1a and 1b, respectively) to 2โ€methoxyโ€__p__โ€benzoquinone (2) gave a mixture of isomeric __endo__ [4 + 2] cycloadducts (3aโ€“3d). Fractional recrystallization of this product mixture from EtOAcโ€hexane gave 6โ€methoxy