Assignment of the mechanism of predissociation of the ClO2 molecule by analysis of single-rotational-level lifetimes
β Scribed by P.A. McDonald; K.K. Innes
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 489 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
We present a theoretical calculation of predissociation lifetimes for the vibrational levels of the H2 molecule in the 2 311a state. Our results predict that vibrational lifetimes decrease with t, up to u= 8 and then remain practically constant. Agreement with available experimental data is good. Fi
In the \(\mathrm{T}\)-shaped \(\mathrm{SiC}_{2}\) molecule, there is experimental evidence that the \(C_{2}\) fragment is bound to the silicium atom by an ionic essentially nondirectional bond, and thus can rotate within the molecule. The \(\nu_{3}\) mode, corresponding to this internal rotation, is
We have observed that the state of the R-branch K=O, v= (0, 10,O) a3Az of CS2 shows two radiative decay curves. For example, for J' = 17 measured at a pressure of 10 mTorr, the two corresponding short and long lifetimes are 0.71 kO.16 and 4.81 kO.13 ps, respectively. The lifetime of individual rotat