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Assignment of the 1H and 13C NMR spectra, sequence and conformation of the synthetic pentasaccharide SanOrg34006 and its precursors

✍ Scribed by Judica Bootsma; Gerard Wagenaars; Erik Dreef; Floris Hout; Edwin Kellenbach

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
109 KB
Volume
39
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Proton and carbon chemical shift data and proton–proton coupling constants of the synthetic antithrombotic pentasaccharide SanOrg34006 and its synthetic precursors are reported. Long‐range heteronuclear correlation experiments allow the determination of the substitution pattern of the protecting groups in the precursor molecules. Also, the sequence of the oligosaccharide was confirmed this way. The conformation of the α‐L‐iduronic acid moiety was studied by the analysis of the ^3^J(^1^H,^1^H) coupling constants. Copyright © 2001 John Wiley & Sons, Ltd.

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