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Assigning vibrational spectra of chaotic molecules

✍ Scribed by Zi-Min Lu; Michael E. Kellman

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
626 KB
Volume
247
Category
Article
ISSN
0009-2614

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✦ Synopsis

A method is presented for detailed level-by-level approximate quantum number assignment and spectral pattern organization for a molecular Hamiltonian with a mixture of regular and chaotic classical dynamics. The large-scale bifurcation structure is determined for a spectroscopic Hamiltonian for H20. A Husimi transform method is used to assign approximate quantum numbers to the levels, and the spectrum is grouped into regular patterns. Pronounced spectral reorganization is observed in the region of most highly chaotic dynamics.

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