✦ LIBER ✦

Assessment of the Electronic Properties of P ligands Stemming from Secondary Phosphine Oxides

✍ Scribed by Dr. David Martin; Dr. Delphine Moraleda; Dr. Thierry Achard; Dr. Laurent Giordano; Prof. Gérard Buono

Book ID: 102797665
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 841 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201101663

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

We report the study of the net donating ability of monodentate and bidentate P ligands stemming from secondary phosphine oxides (SPOs). We experimentally measured and/or calculated the frequencies of CO stretching modes of various metal carbonyl complexes. The inferred electronic properties of the ligands span an unprecedented range, going from π‐accepting phosphite‐like compounds, to extremely electron‐donating ligands outclassing N‐heterocyclic carbenes.

📜 SIMILAR VOLUMES

Synthesis of Tertiary Bisphosphine Oxide

Synthesis of Tertiary Bisphosphine Oxides from Methylacetylene and Secondary Phosphine Oxides

✍ B. A. Trofimov; B. G. Sukhov; S. F. Malysheva; N. A. Belogorlova; S. N. Arbuzova 📂 Article 📅 2004 🏛 SP MAIK Nauka/Interperiodica 🌐 English ⚖ 92 KB

Synthesis of Tertiary Bisphosphine Oxide

Synthesis of Tertiary Bisphosphine Oxides from Methylacetylene and Secondary Phosphine Oxides.

✍ B. A. Trofimov; B. G. Sukhov; S. F. Malysheva; N. A. Belogorlova; S. N. Arbuzova 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 65 KB 👁 1 views

The Concept of P--H Protection Extended

The Concept of P--H Protection Extended to Phosphine Oxides: Preparation of Functional, Unsymmetrical Secondary and Tertiary Phosphine Oxides

✍ Hall, Roger G.; Riebli, Peter 📂 Article 📅 2002 🏛 Taylor and Francis Group 🌐 English ⚖ 89 KB

Effects of secondary ligands on the elec

Effects of secondary ligands on the electronic structure of uranyls

✍ Walch, P. F. 📂 Article 📅 1976 🏛 American Institute of Physics 🌐 English ⚖ 721 KB

The Application of Monodentate Secondary

The Application of Monodentate Secondary Phosphine Oxide Ligands in Rhodium- and Iridium-Catalyzed Asymmetric Hydrogenation.

✍ Xiao-bin Jiang; M. van den Berg; Adriaan J. Minnaard; Ben L. Feringa; Johannes G 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 57 KB 👁 2 views

ChemInform Abstract: Rapid Synthesis of

ChemInform Abstract: Rapid Synthesis of an Electron-Deficient t-BuPHOX Ligand: Cross-Coupling of Aryl Bromides with Secondary Phosphine Oxides.

✍ Nolan T. McDougal; Jan Streuff; Herschel Mukherjee; Scott C. Virgil; Brian M. St 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views