## Measurements of alkyl-lead compounds in air and rain at rural and urban sites in central England during 1996 are reported. Vapour, aerosol and rain concentrations of individual tetra-, tri-and di-alkyl-lead species have been determined simultaneously at both sites, along with inorganic lead aero
Assessment of recent trends in concentrations of alkyl-lead compounds in rainwater
โ Scribed by Alan B Turnbull; Yun Wang; Roy M Harrison
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 536 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0268-2605
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstract
Concentrations of tetraโ, tri and diโalkylโlead compounds in rain have been measured at rural and urban sites in England. The measurements are compared with similar data collected in the early 1980s, prior to a 72% reduction in the emission of lead from combustion of leaded petrol. Whilst concentrations of inorganic lead have fallen broadly in line with emissions of automotive lead, alkylโlead concentrations in rain have fallen by only 50% or less, and thus the ratio of alkylโlead to inorganic lead in rain has increased appreciably. The reason for this phenomenon is unclear. The data suggest that lead in rainwater would fall to approximately 2 ฮผg dm^โ3^ if automotive lead emissions fell to zero.
๐ SIMILAR VOLUMES
A direct derivatization carried out on sediment slurries and simultaneous speciation of organotin and alkyl lead in sediments is described. Simultaneous determination was performed using dual-channel operation of the AED detector. Direct contact of phentylmagnesium bromide with the sediment improved