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Assessing the sequence specificity in the binding of Co(III) to DNA via a thermodynamic approach

✍ Scribed by Michael Hicks; George Wharton III; Daniel H. Huchital; W. Rorer Murphy Jr.; Richard D. Sheardy

Publisher: Wiley (John Wiley & Sons)
Year: 1997
Tongue: English
Weight: 148 KB
Volume: 42
Category: Article
ISSN: 0006-3525
DOI: 10.1002/(sici)1097-0282(19971015)42:5<549::aid-bip5>3.0.co;2-q

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✦ Synopsis

The interaction specificities of Co(III) with DNA were investigated via consideration of thermodynamic characteristics of the duplex to single strand transition for DNA oligomers incubated in the presence of [Co(NH 3 ) 5 (OH 2 )](ClO 4 ) 3 . It has previously been demonstrated that incubation of the DNA oligomer [(5medC-dG) 4 ] 2 with this cobalt complex leads to coordination of the cobalt center to the DNA, presumably at N7 of guanine bases [D.

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