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Assembly of New Coordination Frameworks in a pH-Controlled Medium: Syntheses, Structures, and Properties of 3∞[Cd(Hpdc)(H2O)] and 3∞[Cd3(pdc)2(H2O)2]

✍ Scribed by Long Pan; Xiaoying Huang; Jing Li

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
371 KB
Volume
152
Category
Article
ISSN
0022-4596

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A Reversible Structural Interconversion Involving [M(H2pdc)2(H2O)2]⋅2 H2O (M=Mn, Fe, Co, Ni, Zn, H3pdc=3,5-pyrazoledicarboxylic acid) and the Role of A Reactive Intermediate [Co(H2pdc)2]
✍ Long Pan; Nancy Ching; Xiaoying Huang; Jing Li 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 179 KB 👁 1 views

A new type of hydrogen bonded networks [M(H2pdc)2(H2O)2] . 2H2O [M = Mn (1), Fe (2), Co (3), Ni (4), Zn (5); H3pdc = 3,5-pyrazoledicarboxylic acid] have been synthesized via hydrothermal reactions and their structures have been characterized. Upon a cooling-heating cycle, these compounds undergo a r