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Assembly of an interpenetrating three-dimensional mixed-valence CuII/CuI coordination polymer

✍ Scribed by Hui-Zhong Kou; Bei Chuan Zhou; Ru-Ji Wang


Book ID
108187768
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
436 KB
Volume
689
Category
Article
ISSN
0022-328X

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## Abstract A mixed‐valence copper(I,II) coordination polymer [Cu^I^~2~Cu^II^(4,4′‐bpy)~2~(pydc)~2~]·4H~2~O (4,4′‐bpy = 4,4′‐bipyridine and pydc = pyridine‐2,4‐dicarboxylate) featuring the “metal‐complex ligands” [Cu^II^(pydc)~2~]^2−^ was designed and synthesized hydrothermally from Cu(MeCO~2~)~2~,