Assembled Lanthanide Complexes with Adva
β Yuichi Hirai
π Library
π English
β¦ LIBER β¦
π
Assembled Lanthanide Complexes with Advanced Photophysical Properties
β Scribed by Yuichi Hirai
- Publisher
- Springer Singapore
- Year
- 2018
- Tongue
- English
- Leaves
- 115
- Series
- Springer Theses
- Edition
- 1st ed.
- Category
- Library
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No coin nor oath required. For personal study only.
β¦ Synopsis
This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readersβ fundamental understanding of solid-state photophysics and materials chemistry.
Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4fβ4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.
β¦ Table of Contents
Front Matter ....Pages i-xv
General Introduction (Yuichi Hirai)....Pages 1-14
Luminescent Lanthanide Coordination Zippers with Dense-Packed Structures for High Energy Transfer Efficiencies (Yuichi Hirai)....Pages 15-33
Luminescent Lanthanide-Mixed Coordination Polymers for Tunable Temperature-Sensitivity (Yuichi Hirai)....Pages 35-45
Luminescent Lanthanide Coordination Glasses (Yuichi Hirai)....Pages 47-67
Amorphous Formability and Temperature-Sensitive Luminescence of Lanthanide Coordination Glasses (Yuichi Hirai)....Pages 69-80
Triboluminescence of Lanthanide Coordination Polymers (Yuichi Hirai)....Pages 81-100
Summary and Outlook (Yuichi Hirai)....Pages 101-103
Back Matter ....Pages 105-106
β¦ Subjects
Chemistry; Organometallic Chemistry; Inorganic Chemistry; Tribology, Corrosion and Coatings; Polymer Sciences
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