Aspects of the kinetics and mechanism of the gas-phase reactions of ozone with conjugated dienes
โ Scribed by Lewin, Alison G.; Johnson, David; Price, David W.; Marston, George
- Book ID
- 121399766
- Publisher
- Royal Society of Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 168 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B010006O
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๐ SIMILAR VOLUMES
Rcccivcd 1 1 Au:just 1977 ll~ kinetics ot the grlb plea reaction bctwucn 03 (0.4-15 torr) and IIN (0.002 0.005 torr) hvc been mvcsti~:.!tcti at total pressures of 20-30 torr usmg rl 1m55 spcctromcter dctcctor. No cvldcncc ofa Ilomo~cneous-hllllolc~ul,~r reation was obtarned, and upper limits to the
The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti