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Aspects of tautomerism. Part 16. Influence of the y-keto function on the reactions of sulphonic acids

✍ Scribed by M. S. Shashidhar; M. V. Bhatt

Book ID
112906867
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1989
Tongue
English
Weight
453 KB
Volume
101
Category
Article
ISSN
0253-4134

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The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h