Aspects of tautomerism 12—Some causes and consequences of participation in the solvolysis of acid chlorides
✍ Scribed by M. Vivekananda Bhatt; Vishwanatha Somayaji; M. Vishnumurthi Rao
- Book ID
- 112918128
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1984
- Tongue
- English
- Weight
- 343 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0253-4134
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📜 SIMILAR VOLUMES
The rates of solvolysis in various solvents at 25 °C were determined for five tertiary alkyl chlorides: 2-chloro-2,4,4-trimethylpentane ( 4), 2-chloro-2,4-dimethylpentane, 2-chloro-2-methylpentane, 1-chloro-1,3,3-trimethylcyclopentane (7) and 1-chloro-1-methylcyclopentane. The rate data were analyse
## Abstract The rate constants (log __k__) for the solvolysis of 4^e^‐substituted 2^e^‐ and 2^a^‐adamantyl __p__‐nitrobenzenesulfonates **14** and **15**, respectively, in 80% EtOH correlate linearly with the respective inductive substituent constants σ. Therefore, relative rates are controlled by