Aspects of resonance Raman spectroscopy for the case of a double-well potential
β Scribed by J. M. Leclercq; C. Sandorfy
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 644 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0377-0486
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π SIMILAR VOLUMES
We present a new convergent iterative solution for the two lowest quantum wave functions Ο ev and Ο od of the Hamiltonian with a quartic double-well potential V in one dimension. By starting from a trial function, which is by itself the exact lowest even or odd eigenstate of a different Hamiltonian
The use of ab initio quantum chemical methods to aid in the interpretation of resonance Raman spectra is illustrated with examples where the resonant electronic absorption spectra are unstructured. In such cases only the gradient of the excited electronic state potential energy surface at the ground
## Eigenvalues of the Fokker-Planck and BGK operators for a d2x2/2 + da4/4 double-well potential are ulculated by the matrix continued-fraction method. A dependence of the eigenvalues on the friction constant or coupbng strength is shown for the lowest non-zero real eigenvalue and for some higher,
The electronic structure of a perturbed superlattice of the Bragg-confined resonant structure type is discussed within the effective mass approximation. Expressions for bound-state energies and wavefunctions in these structures are derived in general form, valid for any symmetric form of the potenti