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Aspects of high-conversion free-radically initiated polymerizations: 2. Copolymerization of acrylonitrile with methyl acrylate in dimethylsulfoxide using azobisisobutyronitrile as initiator

✍ Scribed by Masami Takenaka; Anthony F Johnson; Kenji Kamide

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 564 KB
Volume: 35
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(94)90274-7

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## Abstract The free‐radical copolymerization of methyl acrylate with styrene initiated by triphenylstibonium 1,2,3,4‐tetraphenylcyclopentadienylide under nitrogen blanket at (60 ± 0.1)°C in 1,4,dioxane for 2 h has been carried out. The kinetic expression is __R~p~__ ∝ [I]^0.14^ [MA]^0.70^ [Sty]^0.