✦ LIBER ✦
As4S5N10–A Diaminosulfane Derivative with Two Bicyclic Arsino Sulfur Diimides
✍ Scribed by Prof. Dr. Max Herberhold; Dr. Karlheinz Guldner; Prof. Dr. Alfred Gieren; Dipl.-Phys. Catalina Ruiz-Pérez; Dr. Thomas Hübner
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 237 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
OS(CO)~CI( PHPh)( PPhJ2] [W(=CCMe3)Cl2( PHPh)(PEt,),] 3 4
The synthetic utility of magnesium phosphido reagents in gaining access to other metal phosphido complexes is being investigated. Interestingly, reaction of 5 with 1 gave the known diphosphene complex 6"" rather than the expected phosphido [NiCl2I(PR2CH2)d + IMg(PHPh)21 -5 1 [Ni(q-Ph-P= P-Ph)(( PR,CH,)& 6