The cleavage of thioethers by benzyne has been reported previously.2 Ethers have been much
Aryne chemistry part IV tetrachlorobenzyne
β Scribed by H. Heaney; J.M. Jablonski
- Book ID
- 104211811
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 122 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Tetrafluorobensyne shows high reactivity in the formation Of Mels-Alder adducts in good yields with a variety of aromatic substrates. 1,2 It Is of interest, therefore, to compare the reactivity of tetrachlorobenzyne with that of tetrafluorobensyne. The recent suggestions that products obtained from the diasotisation of tetrachloroenthrenilic acid3 end that octachlorobiphenylene , obtained by pyrolysis of tetrachloro;l! ,'i. anhydride4'5, InVOlVe tetraCklOMb~S~e,prOmptS this
π SIMILAR VOLUMES
Skeletal rearrangement under electron impact conditions is of particular significance in the application of mass spectrometry to structure elucidations. In the course of our investigation of the mass spectra\*of pulvic acid derivatives [I -V], certain characteristic rearrangements were observed.
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