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Arylthiols as Highly Chemoselective and Environmentally Benign Radical Reducing Agents

✍ Scribed by Yamago, Shigeru; Matsumoto, Atsushi

Book ID: 127207296
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 188 KB
Volume: 73
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo801200b

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📜 SIMILAR VOLUMES

ChemInform Abstract: Arylthiols as Highl

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## Abstract One‐pot sequential reactions involving azide–alkyne [3+2] cycloaddition and atom transfer radical addition (ATRA) catalyzed by [Cu^II^(TPMA)X][X] {X = Br^–^ or Cl^–^, TPMA = tris(2‐pyridylmethyl)amine} in the presence of ascorbic acid as a reducing agent are reported. Reactions with azi