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Arylation reaction of N-dichlorophosphoryl-P-trichlorophosphazene

✍ Scribed by M. Arslan; F. Aslan; A. I. Ozturk

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
95 KB
Volume
14
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The reactions of N‐dichlorophosphoryl‐P‐trichlorophosphazene (Cl~3~PNPOCl~2~) with phenylmagnesium chloride, o‐tolylmagnesium chloride, p‐tolylmagnesium chloride, p‐chlorophenylmagnesium chloride, 2‐mesitylmagnesium bromide, and 2‐thienyl lithium were studied. The resulting pentaaryl phosphazenes R~3~PNP(O)R~2~ were separated by using column chromatography, their structures were defined by IR, elemental analysis, ^1^H, ^13^C, ^31^P NMR, and mass spectroscopy. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:138–143, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10114

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✍ F. Aslan; A. I. Ozturk; M. Arslan 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 71 KB

## Abstract The reactions of N‐dichlorophosphoryl‐P‐trichlorophosphazene Cl~3~PNP(O)Cl~2~ (**__1__**) with benzylmagnesium bromide, 2‐phenylethylmagnesium bromide, trimethylsilylmethylmagnesium chloride, n‐butylmagnesium bromide, cyclohexylmagnesium bromide, cyclopentylmagnesium bromide, tert‐but