✦ LIBER ✦
Arylation of α-phosphoryl sulfides via their pummerer rearrangement intermediates generated from the corresponding sulfoxides
✍ Scribed by Ioannis K. Stamos
- Book ID
- 104219525
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 154 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Various aryl groups were introduced directly into the a-position of a-phosphoryl sulfides by treating their sulfoxides with trifluoroacetic anhydride and then with tin(IV) chloride in the presence of excess of the aryl compound.