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Arylation and heteroarylation of photochemically generated purinyl radicals

โœ Scribed by Nair, Vasu; Richardson, Stephen G.; Coffman, Robert E.

Book ID
126858611
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
713 KB
Volume
47
Category
Article
ISSN
0022-3263

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CF 3 O 2 CF 3 was photolyzed at 254 nm in the presence of CO in 760 torr N 2 or air at 296 K in a static reactor. In N 2 , the products CF 3 OC(O)C(O)OCF 3 and CF 3 OC(O)O 2 C(O)OCF 3 were detected by FTIR spectroscopy. In air, the only observed products were CF 2 O and CO 2 and a chain process, ini