Aryl-Substituted Sulfonium Betaines: Preparation and Use in the Epoxidation of Aldehydes
β Scribed by Forbes, David C.; Amin, Sejal R.; Bean, Christie J.; Standen, Michael C.
- Book ID
- 120288584
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 76 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01-0.1 mol% Bi(OTf) 3 β’xH 2 O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic C O bond. The highly catalytic nature of this method coupled with the fact t
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