The rearrangement reactions following electron ionization in a number of aryl substituted conjugated nitriles have been studied using labelled compounds and collisional activation (CA) spectroscopy. The results indicate that a- phenyl cinnamonitriles and 9,1Bdihydro-9-cyanophenanthrene rearrange to
Aryl Rearrangements in the Thermolysis of β-Arylated α-Halogenoacrylates
✍ Scribed by Doz. Dr. G. Köbrich; Dipl.-Chem. H. Fröhlich
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 213 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
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A facile synthesis of aryl a-keto esters is reported involving the rearrangement of aryl cyanohydrin carbonate esters induced by the a-carbanion to the nitrile group generated by LDA. However, under similar conditions, an o-benzyloxycyanohydrin carbonate ester rearranged via a domino reaction leadin