A recently published kinetic model of the Belousov-Zhabotinsky reaction was studied by the feature sensitivity analysis of the slow bromide consumption and slow bromide production periods of the relaxing-type oscillatory system. The computed sensitivities allowed us to reveal the kinetic importance
Artificial-intelligence-based interpretation of feature sensitivities of the Belousov-Zhabotinsky reaction
✍ Scribed by L. Györgyi; T. Deutsch; E. Kőrös
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 992 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
A new approach is presented for analyzing kinetic models of relaxation-type oscillatory systems on the basis of numerical data. Feature sensitivities of the length of the two kinetic states of the Belousov-Zhabotinsky (BZ) reaction with respect to the rate constants of the model are explained by means of a logic-based inference system. The main kinetic roles of the individual reaction steps on the relaxing components are revealed, and a consistent interpretation of the kinetic states is given by this process. Both the high and the low set of rate constants were studied. According to our analysis, the bromous acid-hypobromous acid reaction is an important Brproducing step of the model, and in the case of the low set, the bromate-bromous acid reaction is not the rate-determining step of the bromous acid autocatalysis.
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