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Artificial carbohydrate antigens: the synthesis of a tetrasaccharide hapten, a Shigella flexneri O-antigen repeating unit

โœ Scribed by David R. Bundle; Staffan Josephson


Book ID
108308722
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
898 KB
Volume
80
Category
Article
ISSN
0008-6215

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Articial carbohydrate antigens: A block
โœ Hans-Peter Wessel; David R. Bundle ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 714 KB

Glycosylation of methyl 2,4-di-O-benzoyl-alpha-L-rhamnopyranoside with 2,3,4-tri-O-acetyl-alpha-L-rhamnopyranosyl bromide gave methyl 2,4-di-O-benzoyl-3-O-(2,3,4-tri-O-acetyl-alpha-L-rhamnopyranosyl) -alpha-L-rhamnopyranoside (4) in 93% yield. Conversion of 4 into the corresponding glycosyl bromide