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Arsonated Derivatives of Mixed Ketones

✍ Scribed by Omer, Roberta Eleanor; Hamilton, Cliff S.

Book ID
126402199
Publisher
American Chemical Society
Year
1937
Tongue
English
Weight
303 KB
Volume
59
Category
Article
ISSN
0002-7863

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Oxidation of the monohydrazones of a-diketones with yellow mercuric oxide in the presence of base is a weil-known method for the preparation of a-diazo ketones (1). Some years ago, the interestinq observation was made (2) that when this reaction was applied to I, the hydrazone of an a-ketoaldehyde,