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Aromatization of Fulvene by Complexation with Lithium

✍ Scribed by Oziminski, W. P.; Krygowski, T. M.; Fowler, P. W.; Soncini, A.

Book ID
120326066
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
412 KB
Volume
12
Category
Article
ISSN
1523-7060

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The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an i