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Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts

✍ Scribed by Robin J. Nash; Mark E. Dry; Cyril T. O'Connor


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
650 KB
Volume
134
Category
Article
ISSN
0926-860X

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## Abstract The behaviour of catalytic systems based on zirconium compounds for the copolymerization of ethylene with 1‐hexene and 1‐octene is reported. The metallocenes (CH~3~)~2~SiCp~2~ZrCl~2~, Cp~2~ZrCl~2~ (Cp = Ξ·^5^‐cyclopentadienyl), C~2~H~4~[Ind]~2~ZrCl~2~ and (Ind = Ξ·^5^‐indenyl) were chosen

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The interactions between gallium and H-ZSM-5 on gallium-supported H-ZSM-5 catalysts were investigated. Gallium was introduced into H-ZSM-5 by impregnation [Ga/Z5(im)] and physical mixing [Ga/Z5(mix)]. Temperature-programmed desorption studies of ammonia show that the number of strong acid sites (HTP